Universidad de Granada Bionat

 


   

Research Group

Organometallic Chemistry and Molecular Electronic

 


Selected Publications   

2014:

-"Novel ortho-ope metallofoldamers: binding-induced folding promoted by nucleating Ag(I)-alkyne interactions" A. Martín-Lasanta, L. Álvarez de Cienfuegos, A. Johnson, D. Miguel, A. J. Mota, A. Orte, M. J. Ruedas-Rama, M. Ribagorda, D. J. Cárdenas, M. C. Carreño, A. M. Echavarren, J. M. Cuerva Chem. Sci. 2014, 5, 4582-4591.

-"Structural versus electrical functionalization of oligo(phenylene ethynylene) diamine molecular junctions" M. T. González, X. Zhao, D. Z. Manrique, D. Miguel, E. Leary, M. Gulcur, A. S. Batsanov, G. Rubio-Bollinger, C. J. Lambert, M. R. Bryce, N. Agraït J. Phys. Chem. C 2014, 118, 21655–21662.

-"Rational design of a new fluorescent ‘ON/OFF’ xanthene dye for phosphate detection in live cells" A. Martínez-Peragón, D. Miguel, A. Orte, A. J. Mota, M. J. Ruedas-Rama, J. Justicia, J. M. Álvarez-Pez, J. M. Cuerva, L. Crovetto Org. Biomol. Chem. 201412, 6432-6439.

-"Ti(III)-catalyzed cyclizations of ketoepoxypolyprenes: Control over the number of rings and unexpected stereoselectivities" S. P. Morcillo, D. Miguel, S. Resa, A. Martín-Lasanta, A. Millán, D. Choquesillo-Lazarte, J. M. García-Ruiz, A. J. Mota, J. Justicia, J. M. Cuerva J. Am. Chem. Soc. 2014, 136, 6943−6951.

-"Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates" I. Rodríguez-Márquez, A. Millán, A. G. Campaña, J. M. Cuerva Org. Chem. Front. 2014, 1, 373-381.

-"Ti/Ni-mediated inter and intramolecular conjugate addition of aryl and alkenyl halides and triflates" I. Rodríguez-Márquez, D. Miguel, A. Millán, M. L. Marcos, L. Álvarez de Cienfuegos, A. G. Campaña, J. M. Cuerva J. Org. Chem. 2014, 79, 1529–1541.

-"Highly regioselective and chemoselective titanocene mediated Barbier-type allylations" S. P. Morcillo, A. Martínez-Peragón, V. Jakoby, A. J. Mota, C. Kube, J. Justicia, J. M. Cuerva, A. Gansäuer Chem. Commun. 2014, 50, 2211-2213.

-"Recent applications of Cp2TiCl in natural product synthesis" S. P. Morcillo, D. Miguel, A. G. Campaña, L. Álvarez de Cienfuegos, J. Justicia, J. M. Cuerva Org. Chem. Front. 2014, 1, 15-33.

-"Synthesis and photophysics of a new family of fluorescent 9-alkyl substituted xanthenones" A. Martínez-Peragón, D. Miguel, R. Jurado, J. Justicia, J. M. Álvarez-Pez, J. M. Cuerva, L. Crovetto Chem., Eur. J. 2014, 20, 447-455.

2013:

-"The role of water-based hydrogen atom wires in long range electron transfer reactions in aqueous media for the Fe(II)-Fe(III) self-exchange and related systems" A. G. Campaña, E. Buñuel, J. M. Cuerva, D. J. Cárdenas Chem., Eur. J. 2013, 19, 16187-16191.

-"Titanocene(III)-catalyzed 6-exo versus 7-endo cyclizations of epoxypolyprenes: Efficient control and synthesis of versatile terpenic building blocks" J. Justicia, T. Jiménez, D. Miguel, R. Contreras-Montoya, R. Chahboun, E. Álvarez-Manzaneda, Daniel Collado-Sanz, D. J. Cárdenas, J. M. Cuerva Chem., Eur. J. 2013, 19, 14484-14495.

2012:

-"Water control over the chemoselectivity of Ti/Ni multimetallic system: Heck- or reductive-type cyclization reactions of alkyl iodides" A. Millán, L. Álvarez de Cienfuegos, D. Miguel, A. G. Campaña, J. M. Cuerva Org. Lett. 2012, 14, 5984-5987.

-"A versatile bottom-up approach to stapled -conjugated helical scaffolds: Synthesis and chiroptical properties of cyclic o-phenylene ethynylene oligomers" N. Fuentes, A. Martín-Lasanta, L. Álvarez de Cienfuegos, R. Robles, D. Choquesillo-Lazarte, J. M. García-Ruiz, A. J. Mota, L. Martínez-Fernández, I. Corral, D. J. Cárdenas, M. Ribagorda, M. C. Carreño, J. M. Cuerva Angew. Chem. Int. Ed. 2012, 51, 13036-13040.

-"Thermal-driven nanofuses based on organometallic rotors" A. J. Mota, L. Álvarez de Cienfuegos, S. P. Morcillo, N. Fuentes, D. Miguel, S. Rodríguez-Bolívar, F. M. Gómez-Campos, D. J. Cárdenas, J. M. Cuerva ChemPhysChem 2012, 13, 3857-3865.

-"Dichlorobis(cyclopentadienyl)titanium" D. Miguel, A. G. Campaña, J. Justicia, J. M. Cuerva  e-EROS Encyclopedia of Reagents for Organic Synthesis 2012, accepted.

-"Clarifying the structure of granadaene: Total synthesis of  related analogue [2]-granadaene and confirmation of its absolute stereochemistry" M. Paradas, R. Jurado, A. Haidour, J. Rodríguez Granger, A. Sampedro Martínez, M. de la Rosa Fraile, R. Robles, J. Justicia, J. M. Cuerva  Bioorg. Med. Chem. 2012, 20, 6655-6661.

-"Combining the Power of TiIII-mediated Processes for an Easy Access to Hydroxylated Polycyclic Terpenoids. Synthesis of Sesterstatin 1 and C-D Rings of Aspergilloxide" T. Jiménez, S. P. Morcillo, A. Martín-Lasanta, D. Collado-Sanz, D. J. Cárdenas, A. Gansäuer, J. Justicia, J. M. Cuerva Chem., Eur. J. 2012, 18, 12825-12833.

-"Model System for Cell Adhesion Mediated by Weak Carbohydrate−Carbohydrate Interactions" B. Lorenz, L. Álvarez de Cienfuegos, M. Oelkers, E. Kriemen, C. Brand, M. Stephan, E. Sunnick, D. Yüksel, V. Kalsani, K. Kumar, D. B. Werz, A. Janshoff J. Am. Chem. Soc. 2012, 134, 3326-3329.

-"Ti/Ni-Based Multimetallic System for the Efficient Allylation of Carbonyl Compounds" A. Martínez-Peragón, Alba Millán, A. G. Campaña, I. Rodríguez-Márquez, S. Resa, D. Miguel, L. Álvarez de Cienfuegos, J. M. Cuerva  Eur. J. Org. Chem. 2012, 1499-1503.

-"Influence of the Number of Anchoring Groups in the Electronic and Mechanical Properties of Benzene-, Anthracene- and Pentacene-Based Molecular Devices" A. Martín-Lasanta, D. Miguel, T. García, J. A. López-Villanueva, S. Rodríguez-Bolivar, F. M. Gómez-Campos, E. Buñuel, D. J. Cárdenas, L. Álvarez de Cienfuegos, J. M. Cuerva ChemPhysChem 2012, 13, 860-868.

-"H2O-Activation for HAT: Correct Structures and Revised Mechanisms" A. Gansäuer, A. Cangönül, M. Behlendorf, C. Kube, J. M. Cuerva, J. Friedrich, M. van Gastel Angew. Chem. Int. Ed. 2012, 51, 3266–3270.

2011:

-"on/off Electrochemical Switches Based on Quinone-Bisketals" N. Fuentes, L. Álvarez de Cienfuegos, A. Parra, D. Choquesillo-Lazarte, J. M. García-Ruiz, M. L. Marcos, E. Buñuel, M. Ribagorda, M. C. Carreño, D. J. Cárdenas, J. M. Cuerva Chem. Commun. 2011, 47, 1586-1588. This article has received an special metion in the journal Chemicals&Engineering News (see here).

-"Titanium/Palladium-Mediated Regioselective Propargylation of Ketones Using Propargylic Carbontates as Pronucleophiles" A. Millán, L. Álvarez de Cienfuegos, A. Martín-Lasanta, A. G. Campaña, J. M. Cuerva Adv. Synth. Catal. 2011, 353, 73-78.

-"Ti/Pd Bimetallic Systems for the Efficient Allylation of Carbonyl Compounds and Homocoupling reactions" A. Millán, A. G. Campaña, B. Bazdi, D. Miguel, L. Álvarez de Cienfuegos, A. M. Echavarren, J. M. Cuerva Chem., Eur. J. 2011, 17, 3985-3994.

-"Titanocene(III)-Promoted Barbier-type Crotilation of Carbonyl Compounds" I. Sancho-Sanz, D. Miguel, A. Millán, R. E. Estévez, J. L. Oller-López, E. Álvarez-Manzaneda, R. Robles, J. M. Cuerva, J. Justicia J. Org. Chem. 2011, 76, 732-735.

-"Conductance and Application of Organic Molecule Pairs as Nanofuses" S. Rodríguez-Bolívar, F. M. Gómez-Camposa, L. Álvarez de Cienfuegos, N. Fuentes, D. J. Cárdenas, E. Buñuel, J. E. Carcellera, A. Parra, J. M. Cuerva Phys. Rev. B 2011, 83, 125424/1-125424/11.

-"Mild Method for the Selective Esterification of Carboxylic Acids Based on the Garegg-Samuelsson Reaction" S. Morcillo, L. Álvarez de Cienfuegos, A. J. Mota, J. Justicia, R. Robles J. Org. Chem. 2011, 76, 2277-2281.

-"Bioinspired Terpene Synthesis: a Radical Approach" J. Justicia, L. Álvarez de Cienfuegos, A. G. Campaña, D. Miguel, V. Jakoby, A. Gänsauer, J. M. Cuerva Chem. Soc. Rev. 2011, 40, 3525-3537.

-"Reduction Reactions in water, supercritical CO2 and ionic liquids as green solvents" L. Álvarez de Cienfuegos, R. Robles, D. Miguel, J. Justicia, J. M. Cuerva Chem. Sus. Chem. 2011, 4, 1035-1048.

-"Water-based Hydrogen-Atom Wires as Mediators in Long-Range Proton-Coupled Electron Transfer in Enzymes: a New Twist on Water Reactivity" D. J. Cárdenas, J. M. Cuerva, M. Alías, E. Buñuel, A. G. Campaña Chem. Eur. J. 2011, 17, 8318–8323.

-"Organic-based Molecular Switches for Molecular Electronics" N. Fuentes, A. Martín-Lasanta, L. Álvarez de Cienfuegos, M. Ribagorda, A. Parra, J. M. Cuerva Nanoscale 2011, 3, 4003-4014.

-"Ti/Pd-Promoted Intramolecular Michael-type Addition of Allylic Carboxylates to Activated Alkenes" A. Millán, A. Martín-Lasanta, D. Miguel, L. Álvarez de Cienfuegos, J. M. Cuerva Chem. Commun. 2011, 47, 10470-10472.

2010:

-"Unprecedented H-Atom Transfer from Water to Ketyl Radicals mediated by Cp2TiCl" M. Paradas, A. G. Campaña, M. L. Marcos, J. Justicia, A. Haidour, R. Robles, D. J. Cárdenas, J. E. Oltra, J. M. Cuerva Dalton Trans., 2010, 39, 8796-8800.

-"Understanding the Exceptional Hydrogen-Atom Donor Characteristics of Water in TiIII-Mediated Free-Radical Chemistry" M. Paradas, A. G. Campaña, T. Jiménez, R. Robles, J. E. Oltra, E. Buñuel, J. Justicia, D. J. Cárdenas, J. M. Cuerva J. Am. Chem. Soc. 2010, 132, 12748-12756.

-"Mn(0)-Mediated Chemoselective Reduction of Aldehydes. Application to the Synthesis of a-Deuterioalcohols" T. Jiménez, E. Barea, J. E. Oltra, J. M. Cuerva, J. Justicia J. Org. Chem. 2010, 75, 7022-7025.

-"Radical Reduction of Epoxides Using a Titanocene(III)/Water System: Synthesis of β-Deuterated Alcohols and Their Use as Internal Standards in Food Analysis" T. Jiménez, A. G. Campaña, B. Bazdi, M. Paradas, D. Arráez-Román, A. Segura-Carretero, A. Fernández-Gutiérrez, J. E. Oltra, R. Robles, J. Justicia, J. M. Cuerva Eur. J. Org. Chem. 2010, 4288-4295.

2009:

-"Ti-Catalyzed Barbier-type Allylations and Related Reactions" R. E. Estévez, J. Justicia, B. Bazdi, N. Fuentes, M. Paradas, D. Choquesillo-Lazarte, J. M. García-Ruiz, R. Robles, A. Gansäuer, J. M. Cuerva, J. E. Oltra Chem., Eur. J. 2009, 15, 2774-2791.

-"Unexpected TiIII/Mn-Promoted Pinacol Coupling of Ketones" M. Paradas, A. G. Campaña, R. E. Estévez, L. Älvarez de Cienfuegos, T. Jiménez, R. Robles, J. M. Cuerva, J. E. Oltra J. Org. Chem. 2009, 74, 3616-3619.

-"Efficient Propargylation of Aldehydes and Ketones Catalyzed by Titanocene(III)" J. Justicia, I. Sancho-Sanz, E. Álvarez-Manzaneda, J. E. Oltra, J. M. Cuerva Adv. Synth. Catal. 2009, 351, 2295-2300.

-"Mixed Disproportionation versus Radical Trapping in Titanocene(III)-Promoted Epoxide Openings" J. Justicia, T. Jiménez, S. P. Morcillo, J. M. Cuerva, J. E. Oltra Tetrahedron 2009, 65, 10837-10841.

2008:

-"Ti-Catalyzed Reformatsky-Type Coupling between -Halo Ketones and Aldehydes" R. E. Estévez, M. Paradas, A. Millán, T. Jiménez, R. Robles, J. M. Cuerva, J. E. Oltra J. Org. Chem. 2008, 73, 1616-1619.

-"Titanium-Catalyzed Enantioselective Synthesis of a-Ambrinol" J. Justicia, A. G. Campaña, B. Bazdi, R. Robles, J. M. Cuerva, J. E. Oltra Adv. Synth. Catal. 2008, 350, 571-576.

-"Divergent Titanium-Mediated Allylations with Modulation by Nickel or Palladium" A. G. Campaña, B. Bazdi, N. Fuentes, R. Robles, J. M. Cuerva, J. E. Oltra, S. Porcel, A. M. Echavarren Angew. Chem. Int. Ed. 2008, 47, 7515-7519.

-"Ti-catalysed transannular cyclization of epoxygermacrolides. Synthesis of antifungal (+)-tuberiferine and (+)-dehydrobrachylaenolide" J. Justicia, L. Álvarez de Cienfuegos, R. E. Estévez, M. Paradas, A. M. Lasanta, J. L. Oller, A. Rosales, J. M. Cuerva, J. E. Oltra Tetrahedron 2008, 64, 11938-11943.

2007:

-"Unprecedented Hydrogen Transfer from Water to Alkenes and Alkynes Mediated by Ti(III) and Late Transition Metals" A. G. Campaña, R. E. Estévez, N. Fuentes, R. Robles, J. M. Cuerva, E. Buñuel, D. Cardenas, J. E. Oltra Org. Lett. 2007, 9, 2195-2198.

-"Sodium Tetramethoxyborate: An Efficient Catalyst for Michael Additions of Stabilized Carbon Nucleophiles" A. G. Campaña, N. Fuentes, E. Gómez-Bengoa, C. Mateo, J. E. Oltra, A. M. Echavarren, J. M. Cuerva J. Org. Chem. 2007, 72, 8127-8130.

2006:

-"Cp2TiCl in Natural Product Synthesis" J. M. Cuerva, J. Justicia, J. L. Oller-López , J. E. Oltra Top. Curr. Chem. 2006, 264, 63-91.

-"Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by Ti(III) and Other Single-Electron-Transfer Metals?" J. M. Cuerva, A. G. Campaña, J. Justicia, A. Rosales, J. L. Oller-López, R. Robles, D. J. Cardenas, E. Buñuel, J. E. Oltra Angew. Chem. Int. Ed. 2006, 45, 5522-5526.

-"Stereocontrolled Coupling between Aldehydes and Conjugated Alkenals Mediated by TiIII/H2O" R. E. Estévez, J. L. Oller-López, R. Robles, C. R. Melgarejo, A. Gansäuer, J. M. Cuerva, J. E. Oltra  Org. Lett. 2006, 8, 5433-5436.

2005:

-"Enantiospecific Strategy Towards Oxygen-Bridged Terpenoids: Tandem Transannular-Cyclization and Ring-Contraction Processes" A. Rosales, R. E. Estévez, J. M. Cuerva, J. E. Oltra. Angew. Chem. Int. Ed. 2005, 44, 319-322.

-"Convenient Synthesis of Nucleosides and Isonucleoside Analogues" L. Álvarez de Cienfuegos; A. J. Mota, R. Robles. Org. Lett. 2005, 7, 2161-2164.

-"Exploiting Pd(II) and Ti(III) Chemistry To Obtain g-Dioxygenated Terpenoids: Synthesis of Rostratone and Novel Approaches to Aphidicolin and Pyripyropene A" J. Justicia, J. E. Oltra, J. M. Cuerva J. Org. Chem. 2005, 70, 8265-8272.

                                                 

-"7-endo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-Membered Carbocycles" J. Justicia, J. L. Oller-López, A. G. Campaña, J. E. Oltra, J. M. Cuerva, E. Buñuel, D. J. Cárdenas J. Am. Chem. Soc. 2005, 127, 14911-14921.

2004:

-"Titanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry" J. Justicia, A. Rosales, E. Buñuel, J. L. Oller-López, M. Valdivia, A. Haïdour, J. E. Oltra, A. F. Barrero, D. J. Cardenas, J. M. Cuerva. Chem., Eur. J. 2004, 10, 1778-1788.

-"General Approach to Polycyclic Meroterpenoids Based on Stille Couplings and Titanocene Catalysis" J. Justicia, J. E. Oltra, J. M. Cuerva. J. Org. Chem. 2004, 69, 5803-5086.

-"Unprecedented Barbier-type Reactions Catalysed by Titanocene(III)" A. Rosales, J. L. Oller-López, J. Justicia, A. Gansäuer, J. E. Oltra, J. M. Cuerva Chem. Commun. 2004, 2628-2629.

    
 
   

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