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Selected Publications                                                                                   

 

 

E. Barea, C. Montoro y J. A. R. Navarro Toxic gas removal - Metal organic frameworks for the capture and degradation of toxic gases and vapours Chemical Society Reviews, 2014, in the press. DOI:10.1039/C3CS60475F

 

 

S. Rojas, E. Quartapelle-Procopio, F. J. Carmona, M. A. Romero, J. A. R. Navarro, E. Barea Biophysical characterisation, antitumor activity and MOF encapsulation of a half-sandwich ruthenium (II) mitoxantronato system J. Mater. Chem. B, 2014, DOI: 10.1039/C3TB21455A

 

 

N. M. Padial, E. Quartapelle Procopio, C. Montoro, E. López, J. E. Oltra, V. Colombo, A. Maspero, N. Masciocchi, S. Galli, I. Senkovska, S. Kaskel, E. Barea and J. A. R. Navarro

Highly hydrophobic isoreticular porous metal-organic frameworks for the capture of harmful volatile organic compounds. Angew. Chem. Int. Ed. 2013, 52, 8290-8294. DOI: 10.1002/anie.201303484

 

E. Quartapelle Procopio, N. M. Padial, N. Masciocchi, S. Galli, J. E. Oltra, E. Barea and J. A. R. Navarro A Highly Porous Interpenetrated MOF-5 Type Network Based on Bipyrazolate Linkers CrystEngCommun. 2013,  15 (45), 9352 – 9355. DOI: 10.1039/C3CE41339J.

 

 

 

E. Barea, J. A. Navarro, Soft porous coordination polymers in Comprehensive Inorganic Chemistry II, Vol 5. Oxford: Elsevier; 2013. p. 73-102.

 

I. Senkovska, E. Barea, J.A. Rodriguez Navarro, S. Kaskel, Adsorptive capturing and storing greenhouse gases such as sulfur hexafluoride and carbon tetrafluoride using metal-organic frameworks Microporous and Mesoporous Materials, 2012, 156, 115–120.

 

C. Montoro, E. García, S. Calero, M. Pérez-Fernández, A. L. López, E. Barea, J. A. R. Navarro, Functionalisation of MOFs open metal sites with pendant amines for CO2 capture, J. Mater. Chem., 2012, 22, 10155 - 10158. DOI: 10.1039/c2jm16770k

 

 

V. Colombo, C. Montoro, A. Maspero, N. Masciocchi, S. Galli, E. Barea and J. A. R. Navarro,Tuning the Adsorption Properties in Isoreticular Pyrazolate-based Metal-Organic Frameworks Through Ligand Modification. J. Am. Chem. Soc. 2012, 134,12830–12843.

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E. Quartapelle Procopio, T. Fukushima, E. Barea, J. A. R. Navarro, S. Horike, and S. Kitagawa. A soft copper(II) porous coordination polymer with unprecedented aqua bridge and selective adsorption properties. Chem. Eur. J. 2012, 18, 13117–13125.

 

E. Quartapelle Procopio, S. Rojas, N. M. Padial, S. Galli, N. Masciocchi, F. Linares, D. Miguel, J. E. Oltra, J. A. R. Navarro, E. Barea

Study of the incorporation and release of the non-conventional half-sandwich ruthenium(II) metallodrug RAPTA-C on a robust MOF. Chem. Commun. 2011, 47, 11751–11753.

C. Montoro, F. Linares, E. Quartapelle Procopio, I. Senkovska,S. Kaskel,  S. Galli, N. Masciocchi, E. Barea, and J.A.R. Navarro, Capture of Nerve Agents and Mustard Gas Analogues by Hydrophobic Robust MOF-5 Type Metal-Organic Frameworks. J. Am. Chem. Soc. 2011, 133, 11888–11891.

 

E. Barea, F. Turra and J.A.R. Navarro, Gas separation and Purification by MOFs (in Metal-Organic Frameworks. Applications from Catalysis to Gas Storage; D. Farruseng (Ed.)) Wiley-VCH. ISBN 978-3-527-32870-3

 

 

E. Quartapelle-Procopio, F. Linares, C. Montoro, V. Colombo, A. Maspero, E.

Barea, J. A. R. Navarro Cation-Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis Angew. Chem. Int. Ed. 2010, 49, 7308-7311.

 

F. Linares, E. Quartapelle-Procopio, M. A. Galindo, M. A. Romero, J. A. R. Navarro, E. Barea. Molecular Architecture of redox active half-sandwich ruthenium(II) cyclic assemblies. Interactions with biomolecules and anticancer activity. Cryst. Eng. Commun. 2010, 12, 2343-2346.

 

S. Galli, N. Masciocchi, V. Colombo, A. Maspero, G. Palmisano, F.J. López-Garzón, M. Domingo-García, I. Fernández-Morales, E. Barea, and J.A.R. Navarro, Adsorption of harmful organic vapors by flexible hydrophobic bis-pyrazolate based MOFs Chem. Mater. 2010, 22, 1664-1672, DOI: 10.1021/cm902899t

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E. Barea, G. Tagliabue, W.-G. Wang, M. J. Pérez-Mendoza, L. Mendez-Liñan, F. J. López-Garzon, S. Galli, N. Masciocchi, and J. A. R. Navarro,  A Flexible Pro-porous Coordination Polymer: Non-conventional Synthesis and Separation Properties Towards CO2/CH4 Mixture, Chem. Eur. J. 2010, 16, 931-937. DOI: 10.1002/chem.200902346.

 

F. Linares, M. A. Galindo, S. Galli, M. A. Romero, J. A. R. Navarro, E. Barea Coordination Assemblies Based on Dinuclear Half-sandwich Ruthenium(II) Complexes. Non Covalent Binding to DNA and Antitumor Activity Inorg. Chem. 2009, 48, 7413-7420

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N. Masciocchi, S. Galli, G. Tagliabue, A. Sironi, O. Castillo, A. Luque, G. Beobide, W. Wang, M. A. Romero, E. Barea, J. A. R. Navarro,  Thermally-induced interconversions of metal-pyrimidine-4,6-dicarboxylate polymers. A structural, spectroscopic and magnetic study,  Inorg. Chem. 2009, 48,  3087-3094 DOI: 10.1021/ ic802365w

 

Figure

S. Galli, N. Masciocchi, G. Tagliabue, A. Sironi, J. A. R. Navarro, J. M. Salas, L. Mendez, M. Domingo, M. Perez-Mendoza, E. Barea  Polymorphic Coordination Networks Responsive to CO2, Moisture and Thermal Stimuli: Porous Cobalt(II) and Zinc(II) Fluoropyrimidinolates Chem. Eur. J. 2008, 9890-9901

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G. Beobide, W.-G. Wang, O. Castillo, A. Luque, P. Román, U. García-Couceiro, J. P. García-Terán, G. Tagliabue, S. Galli , M. A. Romero, J. A. R. Navarro Manganese(II) pyrimidine-4,6-dicarboxylates: synthetic, structural, magnetic and adsorption insights into the system Inorg. Chem. 2008, 47, 5267-5277.

M. A. Galindo, A. Houlton, W. Clegg, R. W. Harrington, J. Dobado, F. Santoyo-Gonzalez, M. A. Romero, J. A. R. Navarro Electrochemically and Photochemically Active Palladium(II) Heterotopic Metallacalix[3]arenes Chemm. Commun. 2008, 3735 – 3737. DOI: 10.1039/B805705B

J. A. R. Navarro, E. Barea, A. Rodríguez-Diéguez, J. M. Salas, C. O. Ania, J. B. Parra, N. Masciocchi, S. Galli, A. Sironi  Guest-Induced Modification of a Magnetically Active Ultramicroporous, Gismondine-like, Copper(II) Coordination Network   J. Am. Chem. Soc. 2008, 130, 3978-3984. doi: 10.1021/ja078074z

 

TOC_3

E. Barea, A. Rodríguez-Diéguez, J. A. R. Navarro, G. D’Alfonso, A. Sironi [Re2(m-1,2,4-triazolate)2(m-OH)(CO)6]-:  a novel metalloligand for the construction of flexible porous coordination networks Dalton Trans. 2008, 1825-1827.DOI: 10.1039/b800591e

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 M. A. Galindo, M. Quirós, M. A. Romero,  J. A. R. Navarro Cyclic Tetranuclear Half-Sandwich Ruthenium(II) Complexes with 4,7-Phenanthroline and Hydroxo Bridges. Crystal Structure, Solution Behaviour and Binding to Nucleosides  J. Inorg. Biochem. 2008, 102, 1025-1032 doi:10.1016/j.jinorgbio.2007.11.009

 

J.A.R. Navarro, E. Barea, J.M. Salas, N. Masciocchi, S. Galli, A. Sironi, C.O. Ania, J.B. Parra Borderline microporousultramicroporous palladium(II) coordination polymer networks. Effect of pore functionalisation on gas adsorption properties J. Mater. Chem. 2007, 17, 1939 – 1946.

                                                  

J.A.R. Navarro, E. Barea, J.M. Salas, N. Masciocchi, S. Galli, A. Sironi Structural and Magnetic Properties of Layered Copper(II) Coordination Polymers Intercalating s and f Metal Ions. Inorg

. Chem

. 2007, 46, 2988-2997.

 

M.A. Galindo, D. Olea, M.A. Romero, M.J. Hannon, A. Rodger, J. Gómez, P. del Castillo, F. Zamora, J.A.R. Navarro. Design and Non-covalent DNA Binding of Platinum(II) Metallacalix[n]arenes Chem. Eur. J. 2007, 13, 5075-81.

 

N. Masciocchi, S. Galli, A. Sironi, M.A. Galindo, E. Barea, M.A. Romero, J.M. Salas, J.A.R. Navarro, F. Santoyo. Tuning the Structural and Magnetic Properties of Thermally Robust Coordination Polymers. Inorg. Chem. 2006, 45, 7612-7620 

J.A.R. Navarro, E. Barea, J.M. Salas, N. Masciocchi, S. Galli, A. Sironi, J.B. Parra, C.O. Ania. H2, N2, CO, and CO2 Sorption Properties on a Series of Robust Isoreticular Sodalite Type microporous Coordination Polymers. Inorg. Chem. 2006, 45, 2397-2399.

 

E. Barea, M. Quirós, J. A. R. Navarro, J.M. Salas. Heteroleptic Pyrimidine-2-olate and 4,4’-bipyridine Copper(II) Layered Metal-organic Frameworks with Swelling Properties. Dalton Trans. 2005, 1743-1746.

Graphical abstract image for this article  (ID: b500942a)

E. Barea, M.A. Romero, J.A.R. Navarro, J.M. Salas, N. Masciocchi, S. Galli, A. Sironi. Structure, spectroscopic properties and reversible solid to solid reactions of metal complexes of 5-nitropyrimidin-2-olate. Inorg. Chem. 2005, 44, 1472-1481

 

J.A.R. Navarro, J.M. Salas y E. Barea Compuestos de Coordinación Nanoporosos An. Quím. 2005, 101, 31-34.

 

J.A.R. Navarro, E. Barea, M.A. Galindo,  J.M. Salas, M.A. Romero, M. Quirós, N. Masciocchi, S. Galli, A. Sironi and B. Lippert Soft Polynuclear Coordination compounds.J

. Solid State Chemistry, 2005, 178, 2436-2451

S. Galli, N. Masciocchi, E. Cariati, A. Sironi, E. Barea, M.A. Haj, J.A.R. Navarro, J.M. Salas The Quest for SHG-active Coordination Polymers: Synthesis and Properties of Ag(I) Pyrimidinolates. Chem. Mater. 2005, 17, 4815-4824.

 

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M.A. Galindo, S. Galli, J.A.R. Navarro and M.A. Romero Formation of Heterotopic Metallacalix[n]arenes (n = 3, 4, 6) Containing Ethylenediaminepalladium(II) Metal Fragments and 4,7-Phenanthroline and 2-Pyrimidinolate Bridges. Synthesis, Structure and Host-guest Chemistry.  Dalton Trans. 2004, 2780-2785. 

 

 

Graphical abstract image for this article  (ID: B408698H) 

 

 

M.A. Galindo, J.A.R. Navarro, M.A. Romero and M. Quiros. Mononucleotide recognition by cyclic trinuclear palladium(II) complexes containing 4,7-phenanthroline N,N bridgesDalton Trans. 2004, 1563-1566.

 

E. Barea, J.A.R. Navarro, J.M. Salas, N. Masciocchi, S. Galli, A. Sironi. Mineralomimetic Sodalite- and Muscovite-Type Coordination Frameworks. Dynamic Crystal-to-Crystal Interconversion Processes Sensitive to Ion Pair Recognition J. Am. Chem. Soc. 2004, 126, 3014-3015.

E. Barea, J.A.R. Navarro, J.M. Salas, M. Quirós, M. Willermann, B. Lippert, Chiral Pyrimidine Metallacalixarenes: Synthesis Structure and Host-guest Chemistry, Chem. Eur. J. 2003, 9, 4414-4421.

 

E. Barea, J.A.R. Navarro*, J.M. Salas*, N. Masciocchi*, S. Galli, A. Sironi [Cu(4-oxopyrimidinate)2.nH2O]¥: a robust sodalite type metal-organic framework exhibiting a rich host-guest chemistry.Polyhedron, 2003, 22, 3051-3057

 

N. Masciocchi*, S. Galli, A. Sironi, E. Barea, J.A.R. Navarro*, J.M. Salas y L.C. Tabares.Rich structural and magnetic chemistry of cobalt(II) pyrimidin-2-olate and pyrimidin-4-olate complexes. Synthesis, X-ray powder diffraction studies and thermal behavior. Chem. Mater. 2003, 15, 2153-2160.

 

J.A.R. Navarro and B. Lippert  Simple 1:1 and 1:2 complexes of metal ions with heterocycles as building blocks for discrete molecular as well as polymeric assemblies. Coord. Chem. Rev. 2001, 222, 219-250

 

L.C. Tabares, J.A.R. Navarro, J.M. Salas Cooperative guest inclusion by a zeolite analogue coordination polymer. Sorption behavior with gases and amine and group 1 metal salts J. Am. Chem. Soc. 2001, 123, 383-387.

 

J.A.R. Navarro, E. Freisinger and B. Lippert. [(Ethylenediamine)Pt(uracilate)]4, a metal analogue of calix[4]arene. Coordination Chemistry of its 1,3-alternate Conformer towards First Row Transition Metal Ions. Eur. J. Inorg. Chem. 2000, 147-151.    

 

J.A.R. Navarro and J.M. Salas A Palladium Metallacalix[4]arene Capped with a Gadollinium Atom. Chem. Commun. 2000, 235-236.     

 

J.A.R. Navarro, E. Freisinger and B. Lippert Self assembly of Palladium(II) and Platinum(II) complexes of 2-Hydroxypyrimidine to Novel Metallacalix[4]arenes. Receptor Properties Through Multiple H Bonding Interactions. Inorg. Chem. 2000, 39, 2301-2305.

 

J.A.R. Navarro, E. Freisinger and B. Lippert From simple trans-[a2Pt(2-hydroxypyrimidine)2]2+ (a = NH3, CH3NH2) complexes to structures of higher complexity. Molecular recognition of 2-aminopyrimidine by hydrogen bonding. Reactivity towards additional metal ions. Inorg. Chem. 2000, 39, 1059-1065.

 

J.A.R. Navarro, Matthias B.L. Janik, E. Freisinger and B. Lippert [(Ethylenediamine)Pt(uracilate)]4, a metal analogue of calix[4]arene. Coordination and anion host-guest chemistry related to its conformational dynamics. Inorg. Chem. 1999, 38, 426-431.

 

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