Universidad de Granada Bionat

 


   

Research Group

Organic Synthesis

 


Selected Publications   

 

-"Unified Synthesis of Eudesmanolides, Combining Biomimetic Strategies with Homogeneous Catalysis and Free-Radical Chemistry" A. F. Barrero, A. Rosales, J. M. Cuerva, J. E. Oltra. Org. Lett. 2003, 5, 1935-1938.

-"Titanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry" J. Justicia, A. Rosales, E. Buñuel, J. L. Oller-López, M. Valdivia, A. Haïdour, J. E. Oltra, A. F. Barrero, D. J. Cardenas, J. M. Cuerva. Chem., Eur. J. 2004, 10, 1778-1788.

-"General Approach to Polycyclic Meroterpenoids Based on Stille Couplings and Titanocene Catalysis" J. Justicia, J. E. Oltra, J. M. Cuerva. J. Org. Chem. 2004, 69, 5803-5086.

-"Unprecedented Barbier-type Reactions Catalysed by Titanocene(III)" A. Rosales, J. L. Oller-López, J. Justicia, A. Gansäuer, J. E. Oltra, J. M. Cuerva Chem. Commun. 2004, 2628-2629.

-"Enantiospecific Strategy Towards Oxygen-Bridged Terpenoids: Tandem Transannular-Cyclization and Ring-Contraction Processes" A. Rosales, R. E. Estévez, J. M. Cuerva, J. E. Oltra. Angew. Chem. Int. Ed. 2005, 44, 319-322.

-"Convenient Synthesis of Nucleosides and Isonucleoside Analogues" L. Álvarez de Cienfuegos; A. J. Mota, R. Robles. Org. Lett. 2005, 7, 2161-2164.

-"Exploiting Pd(II) and Ti(III) Chemistry To Obtain g-Dioxygenated Terpenoids: Synthesis of Rostratone and Novel Approaches to Aphidicolin and Pyripyropene A" J. Justicia, J. E. Oltra, J. M. Cuerva J. Org. Chem. 2005, 70, 8265-8272.

                                                 

-"7-endo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-Membered Carbocycles" J. Justicia, J. L. Oller-López, A. G. Campaña, J. E. Oltra, J. M. Cuerva, E. Buñuel, D. J. Cárdenas J. Am. Chem. Soc. 2005, 127, 14911-14921.

-"Cp2TiCl in Natural Product Synthesis" J. M. Cuerva, J. Justicia, J. L. Oller-López , J. E. Oltra Top. Curr. Chem. 2006, 264, 63-91.

-"Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by Ti(III) and Other Single-Electron-Transfer Metals?" J. M. Cuerva, A. G. Campaña, J. Justicia, A. Rosales, J. L. Oller-López, R. Robles, D. J. Cardenas, E. Buñuel, J. E. Oltra Angew. Chem. Int. Ed. 2006, 45, 5522-5526.

-"Stereocontrolled Coupling between Aldehydes and Conjugated Alkenals Mediated by TiIII/H2O" R. E. Estévez, J. L. Oller-López, R. Robles, C. R. Melgarejo, A. Gansäuer, J. M. Cuerva, J. E. Oltra  Org. Lett. 2006, 8, 5433-5436.

-"Unprecedented Hydrogen Transfer from Water to Alkenes and Alkynes Mediated by Ti(III) and Late Transition Metals" A. G. Campaña, R. E. Estévez, N. Fuentes, R. Robles, J. M. Cuerva, E. Buñuel, D. Cardenas, J. E. Oltra Org. Lett. 2007, 9, 2195-2198.

-"Sodium Tetramethoxyborate: An Efficient Catalyst for Michael Additions of Stabilized Carbon Nucleophiles" A. G. Campaña, N. Fuentes, E. Gómez-Bengoa, C. Mateo, J. E. Oltra, A. M. Echavarren, J. M. Cuerva J. Org. Chem. 2007, 72, 8127-8130.

-"Ti-Catalyzed Reformatsky-Type Coupling between -Halo Ketones and Aldehydes" R. E. Estévez, M. Paradas, A. Millán, T. Jiménez, R. Robles, J. M. Cuerva, J. E. Oltra J. Org. Chem. 2008, 73, 1616-1619.

-"Titanium-Catalyzed Enantioselective Synthesis of a-Ambrinol" J. Justicia, A. G. Campaña, B. Bazdi, R. Robles, J. M. Cuerva, J. E. Oltra Adv. Synth. Catal. 2008, 350, 571-576.

-"Divergent Titanium-mediated Allylations with Modulation by Nickel or Palladium" A. G. Campaña, B. Bazdi, N. Fuentes, R. Robles, J. M. Cuerva, J. E. Oltra, S. Porcel, A. M. Echavarren Angew. Chem. Int. Ed. 2008, 47, 7515-7519.

-"Ti-Catalyzed Barbier-type Allylations and Related Reactions" R. E. Estévez, J. Justicia, B. Bazdi, N. Fuentes, M. Paradas, D. Choquesillo-Lazarte, J. M. García-Ruiz, R. Robles, A. Gansäuer, J. M. Cuerva, J. E. Oltra Chem., Eur. J. 2009, 15, 2774-2791.

-"Unexpected TiIII/Mn-Promoted Pinacol Coupling of Ketones" M. Paradas, A. G. Campaña, R. E. Estévez, L. Älvarez de Cienfuegos, T. Jiménez, R. Robles, J. M. Cuerva, J. E. Oltra J. Org. Chem. 2009, 74, 3616-3619.

    
 
   

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